Anion-templated assembly of multinuclear copper(II)–triazole complexes

Preeyanuch Sangtrirutnugul             The use of inorganic polyatomic anions such as SiF62– and ClO4– to construct self-assembled high-nuclearity metal complexes is challenging due to their wide range of coordination geometries, sensitivity to pH, and high solvation energies. In this work, the synthesis of hexanuclear Cu(II) complex [Cu6(pytm)6(SiF6)](SiF6)2 (1) [Hpytm = (1-benzyl-1H-1,2,3-triazol-4-yl)(pyridine-2-yl)phenylmethanol] and one-dimensional Cu(II) polymer … Continue reading Anion-templated assembly of multinuclear copper(II)–triazole complexes